Chemical control of hydrodynamic instabilities Chemical reactions can
actively influence, suppress or trigger hydrodynamic
instabilities when they change a physical property of the
fluid (like its density, viscosity or surface tension). We
investigate both experimentally and theoretically the
various reaction-diffusion-convection dynamics induced by
this interplay between chemical reactions and flows
(chemo-hydrodynamics). The objective is to build up general
theories of chemo-hydrodynamic pattern selection and devise
strategies for chemical control of hydrodynamic
instabilities.
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Precipitation patterns in flow conditions When the reactant of a
precipitation reaction is injected into another one at a
given flow rate in a confined geometry, a wealth of
different precipitation patterns can be observed. Our
objective is to analyze the effect of changes in the flow
rate and concentrations on the properties of the various
solid patterns obtained.
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Influence of chemical reactions on CO2 sequestration The dissolution of CO2
into saline aquifers can lead to a buoyantly unstable
stratification of denser CO2-enriched brine on
top of less dense pure brine, giving rise to fingers rich in
CO2 sinking in the host phase. This convective
dissolution is favorable to the sequestration of CO2
as it can significantly enhance the dissolution rate of CO2
into the brine, reducing mixing times from thousands to
hundreds of years. Our objective is to analyze the influence
of chemical reactions on this convective dissolution by
combined experimental and theoretical approaches.
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Buoyancy-driven instabilities in reactive systems The interface between two
miscible or partially miscible fluids can become unstable
because of density differences like in the Rayleigh-Taylor
instability developing when a denser fluid overlies a less
dense one in the gravity field. Similarly, differential
diffusion processes can trigger convective instabilities of
miscible interfaces because of the presence of different
solutes impacting the density that have different diffusion
coefficients. We study by combined experiments and
theoretical approaches, the properties of the related
convective mixing in two-layer systems both with or without
reactions.
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Viscous fingering in non ideal and reactive systems Viscous fingering is a
hydrodynamic instability developing in porous media when a
fluid of lower viscosity displaces another more viscous one.
The interface between the two fluids then deforms into
fingers growing in time. Such a fingering instability is
detrimental to fluid displacements in oil recovery
techniques, contaminant transport in aquifers, in packed bed
reactors, and in chromatographic separation techniques. Our
goal is to investigate theoretically the influence of
viscous fingering on the spreading of viscous samples in the
presence of non ideal mixing or chemical reactions.
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Convective processes during sea ice growth As sea ice grows from sea
water, the salt dissolved in the liquid phase is rejected
from the solid phase. There is current interest to
understand the transport processes at the origin of this
expulsion of brine out of the sea ice due to their impact on
global climate processes. Highly saline brine sinking from
sea ice is indeed a driver of global thermohaline
circulation whilst convective movements of brine within the
ice also influence the movement of gases and nutrients,
which affect the Arctic ecosystem. Our objective is to
analyze and quantify these convective movements within and
below the ice by combined experimental and numerical
techniques.
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Pattern formation in reaction-diffusion systemsPhysico-chemical systems
driven far from equilibrium by mass or energy fluxes may
develop space or time symmetry breaking bifurcations that
lead to time dependent oscillations or space periodic
dissipative structures. We investigate theoretically the
conditions of appearance of such symmetry breaking
instabilities as well as the resulting nonlinear
spatio-temporal dynamics. Our results encompass pattern
selection theories of 2D and 3D Turing patterns and an
analysis of the dynamics resulting from the coupling between
Turing and Hopf instabilities. Our current interest lies in
the analysis of spatio-temporal dynamics around
reaction-diffusion fronts in presence of reactant
concentration gradients or radial injection.
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